Showing posts with label Cooling Tower. Show all posts
Showing posts with label Cooling Tower. Show all posts

A Marley mechanical induced draft cooling tower

 

The heat absorbed by the circulating cooling water in the condenser tubes must also be removed to maintain the ability of the water to cool as it circulates.

This is done by pumping the warm water from the condenser through either natural draft, forced draft or induced draft cooling towers.

The cooling water used to condense the steam in the condenser returns to its source without having been changed other than having been warmed. If the water returns to a local water body (rather than a circulating cooling tower), it is tempered with cool 'raw' water to prevent thermal shock when discharged into that body of water.

Another form of condensing system is the air-cooled condenser. The process is similar to that of a radiator and fan. Exhaust heat from the low pressure section of a steam turbine runs through the condensing tubes, the tubes are usually finned and ambient air is pushed through the fins with the help of a large fan. The steam condenses to water to be reused in the water-steam cycle. Air-cooled condensers typically operate at a higher temperature than water cooled versions. Whilst saving water, the efficiency of the cycle is reduced (resulting in more carbon dioxide per MW of electricity).

In cooling tower water, to reduce pH we are using sulphuric acid and what is the adverse effect if we use Hydro chloric acid ?

When makeup water sulfate is high and/or the tower is operated at high cycles, sulfuric acid feed can lead to calcium sulfate scaling. Sometimes, hydrochloric acid is used instead of sulfuric acid in such cases. However, this can result in high chloride levels, which often contribute significantly to increased corrosion rates-especially pitting and/or stress cracking of stainless steel.

Cooling Water Treatment : NaOCl Vs ClO2

For the cooling water treatment in cooling tower chlorine is required and that can be obtained in many forms.


ClO2 (Chlorine Dioxide)
NaOCl(Sodium Hypochlorite)
Production
The first is the most common method of generating ClO2 is through the reaction of chlorine gas with a solution of sodium chlorite.
2NaClO2
+
Cl2
  
2ClO2
+
2NaCl
sodium chlorite

chlorine dioxide

chlorine

sodium chloride









Theoretically, 1 lb of chlorine gas is required for each 2.6 lb of sodium chlorite. However, an excess of chlorine is often used to lower the pH to the required minimum of 3.5 and to drive the reaction to completion. Sodium hypochlorite can be used in place of the gaseous chlorine to generate chlorine dioxide. This process requires the addition of sulfuric or hydrochloric acid for pH control. If allowed to dry Liquid NaClO2, this powerful oxidizing agent forms a powdered residue that can ignite or explode if contacted by oxidizable materials.
- By dissolving salt in softened water, which results in a concentrated brine solution. The solution is electrolyzed and forms a sodium hypochlorite solution in water. This solution contains 150 g active chlorine (Cl2) per liter. During this reaction the explosive hydrogen gas is also formed.
The second is the possibility to order Chlorine dioxide in its stabilised form (SCD). SCD is activated on-site whenever its usage is desirable. It can be dosed into an existing or new process where disinfection is required. This makes it an easy-to-use, safe and versatile disinfectant.
- By adding chlorine gas (Cl2) to caustic soda (NaOH). When this is done, sodium hypochlorite, water (H2O) and salt (NaCl) are produced according to the following reaction:
Cl2 +2NaOH
→ NaOCl+ NaCl+ H2O
Process
Chlorine dioxide is generally applied directly into the suction of the cooling system's recirculating pump. Alternatively, it may be applied beneath the water in the sump as close to the pump intake as possible.
Sodium hypochlorite solution is diluted with water in a mixing/holding tank. The diluted solution is injected by a chemical pump into the water supply pipe at a controlled rate. Adequate mixing and contact time
must be provided
Advantages
It is a very powerful disinfectant and biocide; Unlike chlorine, Chlorine dioxide is effective at pH between 4 and 10. No dumping and filling with fresh water required; The corrosive effects of chlorine dioxide are minimal compared to the corrosive effects of plain tap water; The bactericidal efficiency is relatively unaffected by pH values between 4 and 10. Acidisation, therefore is not required; Chlorine dioxide can be used as a spray. All parts therefore, can easily be reached; And last but not least: less environmental impact. Chlorine dioxide an excellent choice for cooling water that has a high pH, or that has high levels of organic or ammoniacal contamination.
It can easily and be stored and transported when it is produced on-site. Dosage is simple. Transport and storage of sodium hypochlorite are safe. Sodium hypochlorite is as effective as chlorine gas for disinfection. Sodium hypochlorite produces residual disinfectant.
Disadvantages
Rather than hydrolyzing in water as chlorine does, chlorine dioxide forms a true solution in water under typical cooling tower conditions. For this reason, chlorine dioxide is volatile (700 times more volatile than HOCl) and may be easily lost from treated water systems, especially over cooling towers
Due to the presence of caustic soda in sodium hypo chlorite, the pH of the water is increased.
The stability of hypochlorite solutions is adversely affected by heat, light, pH, and metal contamination. The rate of decomposition of 10% and 15% solutions nearly doubles with every 10°F rise in the storage temperature. Sunlight reduces the half-life of a 10%-15% hypochlorite solution by a factor of 3 to 5. If the pH of a stored solution drops below 11, decomposition is more rapid. As little as 0.5 ppm of iron causes rapid deterioration of 10-15% solutions. The addition of concentrated ferric chloride to a tank of sodium hypochlorite causes the rapid generation of chlorine gas.
Normal industrial grades of sodium hypochlorite may be fed neat or diluted with low-hardness water. The use of high-hardness waters for dilution can cause precipitation of calcium salts due to the high pH of the hypochlorite solution.
Hypochlorite solutions decompose and should not be stored for more than one month. It must be stored in a cool, dark, dry area.
Safety Issues
Chlorine dioxide is explosive under pressure. It is difficult to transport and is usually manufactured on site. Chlorine dioxide is usually produced as a watery solution or gas. As a gas, chlorine dioxide is more irritating and toxic. Chlorine dioxide in air is detectable by odor at 14-17 ppm, irritating at 45 ppm, fatal in 44 min at 150 ppm, and rapidly fatal at 350 ppm. Concentrations greater than 14% in air can sustain a decomposition wave set off by an electric spark.
Sodium hypochlorite is a dangerous and corrosive substance. While working with sodium hypochlorite, safety measures have to be taken to protect workers and the environment. Sodium hypochlorite should not come in contact with air, because that will cause it to disintegrate.
Sodium hypochlorite should be stored with care and kept away from equipment that can be damaged by corrosion.
Equipment

A basic liquid chlorination system, or hypochlorinator, includes two
metering pumps (one serving as a
standby), a solution tank, a diffuser (to inject the solution into the water), and tubing.
Quantity

Approximately 1 gal of industrial strength sodium hypochlorite is required to replace 1 lb of gaseous chlorine.

Cooling Tower - Energy Saving Measures

Energy saving measures in Cooling Tower : - A lot of energy can be saved during operation of cooling tower by taking following measures
• Stop cooling water flow through non-operating/ idling equipments
• Process integration and heat exchanger networking to reduce the cooling load
• Periodical cleaning of heat exchanger
• Optimize cooling water flow to maintain design dT across the heat exchanger
• Reduce the operating hours of fans based on temperature
• Provide hollow energy efficient FRP blades
• Adjust blade angle to suit the requirement
• Provide two speed motors where ever applicable
• Fills have to be maintained in perfect condition
• Periodically replace/clean choked or damaged nozzles.

What all the water losses in cooling tower


The Water losses in Cooling Tower are :
  • Drift loss - due to drift
  • Evaporation loss - due to evaporation
  • Blowdown loss -
Thumb rule : evap loss – 1% of quantity of circulating water, 
blowdown loss – 1% of quantity of circulating water